tldr; no, if you trust your vpn more than your ISP always use it, as any hit to fingerprinting is menial.
it really can't hurt much to always be using it. any fingerprinting metric it would give is outweighed by the hiding of your IP behind the proxy. this is the #1 unique identifier that is tied back to people/locations.
the other fingerprinting metrics also are still exposed anyway & could probably be linked back to "you" regardless of your IP changing if they wanted too.
if you are worried about fingerprinting look into some projects like mullvad, librewolf, or even tor. clearing cookies on quit &/or having a separate browser for permenant logins/tokens to live in is also a good mitigation technique.